Charge Generation Processes in Organic Solar Cells
Natalie Banerji a
a Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland.
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Invited Speaker, Natalie Banerji, presentation 215
DOI: https://doi.org/10.29363/nanoge.hopv.2023.215
Publication date: 30th March 2023

The objective of my group is to use ultrafast spectroscopic techniques, such as transient absorption (TA) and time-domain terahertz (TD-THz) spectroscopies, to investigate charge carriers in organic photovoltaic (OPV) materials. While femtosecond TA measurements bring insights to the nature and evolution of the photoexcited species, we use TD-THz spectroscopy to gain information about the charge transport properties on the nanoscale. In this talk, I will present an overview of our results obtained in recent years about the different steps of charge generation in OPVs. After presenting our experimental techniques, I will show results about charge generation in highly efficient solar cell materials based on organic polymer:fullerene [1] and polymer:non-fullerene blends [2] with negligible driving force for interfacial charge transfer, as well as on evaporated dilute solar cells [3]. I will discuss how charge generation and recombination processes depend on parameters such as the charge transfer driving force, the short-range charge mobility and the morphology. The combination of our results allows to visualize all relevant processes that lead to efficient charge extraction in full devices.

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