Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
DOI: https://doi.org/10.29363/nanoge.hopv.2023.215
Publication date: 30th March 2023
The objective of my group is to use ultrafast spectroscopic techniques, such as transient absorption (TA) and time-domain terahertz (TD-THz) spectroscopies, to investigate charge carriers in organic photovoltaic (OPV) materials. While femtosecond TA measurements bring insights to the nature and evolution of the photoexcited species, we use TD-THz spectroscopy to gain information about the charge transport properties on the nanoscale. In this talk, I will present an overview of our results obtained in recent years about the different steps of charge generation in OPVs. After presenting our experimental techniques, I will show results about charge generation in highly efficient solar cell materials based on organic polymer:fullerene [1] and polymer:non-fullerene blends [2] with negligible driving force for interfacial charge transfer, as well as on evaporated dilute solar cells [3]. I will discuss how charge generation and recombination processes depend on parameters such as the charge transfer driving force, the short-range charge mobility and the morphology. The combination of our results allows to visualize all relevant processes that lead to efficient charge extraction in full devices.