Charge transfer and structural control in block co-polymer OPVs
Jolanda Muller a
a Department of Physics & Centre for Processable Electronics, Imperial College London, UK
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Oral, Jolanda Muller, presentation 207
DOI: https://doi.org/10.29363/nanoge.hopv.2023.207
Publication date: 30th March 2023

The efficiencies of organic photovoltaics (OPVs) - while lower than the conventional silicon solar cells - have seen a sharp increase in recent years thanks to the development of new non-fullerene acceptors. However, achieving long-term performance stability in the higher efficiency OPVs is still challenging. This is because best performing bulk heterojunction devices are based on blends of different materials that demix when exposed to light and heat, leading to a strong reduction in conversion efficiency after as little as a few hours in some cases (Mateker & McGehee, 2017). A promising approach to tackle the stability issue is the use of single-component macromolecular semiconductors (Review by Roncali, 2021), which have recently showed significant improvements in conversion efficiency reaching >11% in a block co-polymer system while maintaining good performance stability (Wu et al., 2021). By combining the state-of-the art polymer donors and non-fullerene acceptors into block co-polymers, we hope to gain a deeper physical understanding of how charge generation and transport works in those systems. For this we are investigating block co-polymer systems based on the PBDB-T and PYT material groups. On the one hand we are using chemical modifications to the building blocks of the polymers to tune the energetics in the system in order to understand the interplay between through-space and through-bond charge transfer. On the other hand, we are modifying the large-scale structure of the polymers by tuning the length of the donor and acceptor segments to make a comparison to the polymer-polymer bulk heterojunction. These new material systems are analysed using optoelectronic measurements and modelling to better understand the morphological ordering in block co-polymers and the impact the morphology has on the device properties. Combining the advances in efficiency thanks to novel chemical design of donors and acceptors with the long-term stability of the block co-polymer structure will hopefully lead to more industrially viable alternatives to the popular bulk heterojunction devices (He et al., 2022).

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