Overcoming Ionic Migration in Perovskite Solar Cells: Recombination, Negative Capacitance and High Photovoltage
Clara Aranda a b, Agustin Alvarez a, Monika Rai b, Chittaranjan Das b, Michael Saliba b
a Institute of Advanced Materials (INAM) Universitat Jaume I (UJI) 12006, Castelló de la Plana, Castellón, Spain
b Institute for Photovoltaics (ipv), University of Stuttgart, Pfaffenwaldring 47, 70569, Stuttgart, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Oral, Clara Aranda, presentation 162
DOI: https://doi.org/10.29363/nanoge.hopv.2023.162
Publication date: 30th March 2023

Photovoltage losses in perovskite solar cells are associated with an insufficient understanding of interfacial recombination dynamics. For wide band-gap (2.3 eV) materials, these loses still represent around 0.4 eV with respect to the theoretical voltage at the radiative limit1  which makes them excellent candidates to study these processes in depth. On the other hand, the interest in improving the performance of these materials has grown enormously, due to their potential applications in tandem cells, LEDs technologies and even in electrochemical reactions.2 In this work is presented the role of cationic additives in both electronic and ionic charges distribution and how they can modulate them to reach high photovoltages.3 Using them as sentinels, we find the common origin of two features corresponding to unwanted recombination processes: (i) inverted hysteresis during current-voltage measurements and (ii) inductive processes detectable through impedance spectroscopy, (i.e; negative capacitance).4 The cationic additives can reduce these processes leading to an outstanding record value of 1.65 V for a methylammonium lead bromide perovskite solar cell. Through time-of-flight secondary ion mass spectrometry, X-ray photoelectron spectroscopy and impedance spectroscopy, we have revealed the interaction behind this reduction, unveiling an ionic modulation effect as responsible for this achievement.

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