Materials Forming Self-Assembling Monolayers: Pathway to Efficient Solar Cells
Artiom Magomedov a, Mantas Marcinskas a, Yuanbao Lin b, Amran Al-Ashouri c, Eike Köhnen c, Tadas Malinauskas a, Thomas Anthopoulos b, Steve Albrecht c, Vytautas Getautis a
a Kaunas University of Technology, Kaunas, 50254, Lithuania
b KAUST Solar Center, Thuwal 23955, Saudi Arabia
c Helmholtz-Zentrum Berlin, Berlin, 12489, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Oral, Tadas Malinauskas, presentation 132
DOI: https://doi.org/10.29363/nanoge.hopv.2023.132
Publication date: 30th March 2023

In the future production of energy will strongly rely on direct light-to-electricity transformation. For the foreseeable future Si-based technologies could be adequate, however, for the further progress higher efficiencies, simpler fabrication and lower costs are needed. Recently significant progress was made in perovskite-based and organic photovoltaics which promise benefits of low cost, high efficiency and large versatility and can potentially be manufactured in a cost-effective fashion. One of the possible pathways to boost the performance and stability of solar cells is improvement in the efficiency of carrier extraction by corresponding charge-transport layers, key components in modern optoelectronic devices.

In our work we have proposed a new way to form a charge selective layer by utilizing the ability of certain organic materials to spontaneously form a monolayer on various surfaces. Use of the carbazole chromophore provides good selectivity for holes, while phosphonic acid group ensures strong binding to the substrate, for example metal oxides.

While initially this idea was mostly driven by scientific curiosity, soon it became clear that it can compete with conventional polymeric and small molecule hole transporting materials. The full potential was demonstrated in various tandem technologies, where world records were achieved (Si/Perovskite [1], CIGS/Perovskite [2], Perovskite/OPV [3]). In addition, this technology allowed to achieve one of the highest efficiencies for OPV [4].

Co-funded by the European Union under the Horizon Europe grant 101084251 (PEPPERONI).

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