Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
DOI: https://doi.org/10.29363/nanoge.hopv.2023.118
Publication date: 30th March 2023
With the advent of non-fullerene acceptors, breaking the 20 % power conversion efficiency limit is within close reach for organic solar cells. Understanding the efficiency-limiting processes remains important.
I will discuss how losses in the fill factor can be due to the transport resistance, a voltage loss because of a low conductivity in the active layer. Its relevance for organic solar cells was only shown a half dozen years ago [1]. I will present transport resistance limiting different organic solar cell types, and then focus on fresh and thermally degraded PM6:Y6 solar cells (heated to 85°C, in the dark, under nitrogen atmosphere), a state-of-the-art system based on the non-fullerene Y6. The increasing fill factor losses on this degradation path are because of the transport resistance [2]. The reason seems to be trap formation in the tail states, which decrease the active layer conductivity. I will show that the transport resistance as fill factor loss is also prominent in other organic solar cells types, not just degraded but also fresh ones.