Understanding Degradation Mechanism in Organic Solar Cells
Thuc-Quyen Nguyen a
a Center for Polymers and Organic Solids and Department of Chemistry and Biochemistry University of California, Santa Barbara
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Keynote, Thuc-Quyen Nguyen, presentation 111
DOI: https://doi.org/10.29363/nanoge.hopv.2023.111
Publication date: 30th March 2023

Organic solar cells (OSCs) potentially can offer low cost, large area, flexible, light-weight, clean, and quiet alternative energy sources for indoor and outdoor applications. OSCs using non-fullerene acceptors (NFAs) have garnered a lot of attention during the past few years and shown dramatic increases in the power conversion efficiency (PCE). PCEs higher than 19% for single-junction systems have been achieved, but the device lifetime is still too short for practical applications. Thus, understanding the degradation mechanisms in an OSC is crucial to improve its long-term stability. In this talk, I will discuss the degradation mechanisms in organic solar cells based on PM6:Y6. We investigated different device structures on the device lifetime. A combination of characterization methods such as solid state Nuclear Magnetic Resonance (NMR), resonant soft X-ray scattering (RSoXS), AFM, X-ray photoelectron spectroscopy (XPS), Electron paramagnetic resonance (EPR) spectroscopy, and capacitance spectroscopy are employed to gain insight into the device degradation.

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