Tailoring Crystal Orientation and Passivating Surface Defects for Efficient 2D Ruddlesden-Popper Perovskite Solar Cells
Ju-Hyeon Kim a b, Heejoo Kim b c, Kwanghee Lee a b
a School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Gwangju 61005, Republic of Korea
b Heeger Center for Advanced Materials & Research Institute for Solar and Sustainable Energies, Gwangju Institute of Science and Technology
c Graduate School of Energy Convergence Institute of Integrated Technology, Gwangju Insititute of Science and Technology, Gwangju 61005, Republic of Korea
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Poster, Ju-Hyeon Kim, 033
Publication date: 30th March 2023

Quasi-2D Ruddlesden-Popper phase perovskite (RPP) materials have attracted research interest as emerging semiconductor materials in the optoelectronic field owing to their unique photophysical properties and superior environmental stability. However, despite considerable research on RPP-based perovskite solar cells (PSCs) using various methods, the photovoltaic performance of RPP-based PSCs is still behind those of their 3D counterparts. This performance gap is mainly caused by photogenerated charge carrier loss in the PSCs. In this work, we successfully demonstrate efficient RPP-based PSCs by employing simple post-treatment of a multifunctional molecule on the top surface of the RPP materials (with an RPP composition of PEA2MA4Pb5I16 <n> = 5) in a planar p-i-n configuration of PSCs. Our new strategy significantly passivated both the surface and deep-level trap sites of the RPP materials by electrostatic interactions and simultaneously induced out-of-plane crystal orientations. Due to this novel surface engineering, the carriers generated from RPP photoactive materials were effectively transported in both the bulk material and at the interfaces in PSCs, leading to minimal carrier loss. As a result, we achieved a high power conversion efficiency (PCE) of 20.05% with negligible hysteresis in the RPP-based PSCs. Furthermore, our optimal devices exhibited excellent operational stability over 1000 hours, maintaining almost 88% of the initial PCE under continuous AM 1.5G 1-sun irradiation and a maximum power point tracking system (without a UV filter and encapsulation).

J.-H. K. thanks the Heeger Center for Advanced Materials (HCAM) at the Gwangju Institute of Science and Technology (GIST) for assistance with device fabrication and analysis. This work was supported by the Technology Development Program to Solve Climate Change of the National Research Foundation (NRF) funded by MSIT (NRF-2020M1A2A2080748); by the NRF funded by MSIT (No. 2020R1A2C3003653)

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