Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
DOI: https://doi.org/10.29363/nanoge.hopv.2023.027
Publication date: 30th March 2023
Dye-sensitised solar cells have recently attracted increasing interest as devices for ambient light harvesting, with reported efficiencies now reaching 37% under indoor light [1]. A remaining challenge however is the comparatively poor stability of devices containing a liquid electrolyte. One approach to overcome this involves drying of the Cu-complex based electrolyte to give a solid-state, so-called “zombie”, cell [2]. Although these can reach good efficiencies, the drying process is currently slow and poorly reproducible, thus impractical for real-world use.
We have fabricated solid-state DSSCs by simply drying out the common liquid I-/I3- electrolyte [3], and have demonstrated power-conversion efficiency for the solid-state cells over 5%, similar to that of the parent liquid cell before drying. In indoor light conditions (1000 Lux), power-conversion efficiencies were around 20%. We observed negligible degradation of efficiency after 12 months dark storage without encapsulation. Furthermore, we have developed a rapid process for cell fabrication, enabling larger area devices made on an open bench [4]. We believe these findings establish a unique new approach to making very simple, stable, solid-state DSSCs of potential practical application, with efficiency that might be optimisable up to around 10%.