Simple, Stable, Efficient Solid-State Dye-Sensitized Solar Cells Based on Polyiodides
Neil Robertson a
a School of Chemistry, University of Edinburgh, West Mains Rd, Edinburgh, EH9 3FJ, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Oral, Neil Robertson, presentation 027
DOI: https://doi.org/10.29363/nanoge.hopv.2023.027
Publication date: 30th March 2023

Dye-sensitised solar cells have recently attracted increasing interest as devices for ambient light harvesting, with reported efficiencies now reaching 37% under indoor light [1]. A remaining challenge however is the comparatively poor stability of devices containing a liquid electrolyte. One approach to overcome this involves drying of the Cu-complex based electrolyte to give a solid-state, so-called “zombie”, cell [2]. Although these can reach good efficiencies, the drying process is currently slow and poorly reproducible, thus impractical for real-world use.

We have fabricated solid-state DSSCs by simply drying out the common liquid I-/I3- electrolyte [3], and have demonstrated power-conversion efficiency for the solid-state cells over 5%, similar to that of the parent liquid cell before drying. In indoor light conditions (1000 Lux), power-conversion efficiencies were around 20%. We observed negligible degradation of efficiency after 12 months dark storage without encapsulation. Furthermore, we have developed a rapid process for cell fabrication, enabling larger area devices made on an open bench [4]. We believe these findings establish a unique new approach to making very simple, stable, solid-state DSSCs of potential practical application, with efficiency that might be optimisable up to around 10%.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info