Low Synthetic Complexity Donor Polymers
Martin Heeney a b, Martina Rimmele b, Zhuoran Qiao b, Nicola Gasparini b
a KAUST Solar Center, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia., Al-Jabriah, Yanbu Arabia Saudita, Yanbu, Saudi Arabia
b Department of Chemistry, Imperial College London, Wood Lane, 80, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV23)
London, United Kingdom, 2023 June 12th - 14th
Organizers: Tracey Clarke, James Durrant and Trystan Watson
Oral, Martin Heeney, presentation 006
DOI: https://doi.org/10.29363/nanoge.hopv.2023.006
Publication date: 30th March 2023

The overall efficiency of organic photovoltaic devices has made impressive progress in recent years. However, in many cases the active materials now require complex, multi-step synthesis, potentially limiting their synthesis at large scale. Here I will discuss approaches to readily synthesise monomeric building blocks in just one or two steps. Such approaches allow the preparation of (donor) polymers of low synthetic complexity which can be readily upscaled. I will highlight how this approach can be used to readily build libraries of monomer of which a variety of different sidechains. Co-polymerisation of such monomers allows the preparation of polymer libraries with systematic variations. Using one such library we investigate how sidechains influence a variety of polymer properties, such as solubility, surface energy, self-assembly and device performance. This allows the identification of a donor which can be readily synthesis and affords a device efficiency greater than 15% when combined with a low band gap non-fullerene acceptor.

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