Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV22)
Publication date: 20th April 2022
Organic-inorganic hybrid perovskite exhibits outstanding properties in light emission and photovoltaic applications, exceeding conversion efficiencies of 25%, and fast photodetection response [1]. Thus, considering the size-dependent optical and electronic properties of these materials, the use of perovskite nanocrystals helps to mitigate bulk related issues such as photoinduced halide segregation and crystal phase instability [2]. However, some challenges still need to be addressed in terms of device fabrication, particle aggregation, annealing and post-treatment related issues, and environmental instability when assembled [3]. Therefore, using a metal-organic host matrix based on a sol-gel approach [4] as a straightforward method for the in-situ and controlled generation of highly stable perovskite nanocrystals (PNCs) stands out as a promising alternative. The optical and electrical properties of these materials are evaluated to enlighten the specific characteristics of this system concerning a perovskite polycrystalline thin film, showing photoluminescence quantum yield exceeding 80%, photocurrent response with an ON/OFF current ratio around two orders of magnitude, and remarkable stability over time when stored under room conditions. We believe that our antisolvent and glovebox-free approach for the preparation of PNCs will pave the road for its application in perovskite photodetectors, among other devices as sensors, and light emitters.