Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV22)
Publication date: 20th April 2022
In recent years, dye-sensitized solar cells (DSSCs) have received much interest as low-cost photovoltaic devices compared to traditional silicon solar cells. The development of these prospective low-cost solar cells focuses on finding efficient dyes and charge-transport materials for tandem DSSCs. Modifying the p-DSSC conversion efficiency would have a major impact on the molecular level performance of solar cells. This work focuses on the organic synthesis, characterization, electrochemical and photophysical properties of a series of compounds comprising a fullerene (C60) as electron transport mediators for application in dye-sensitized solar cells (DSSCs). Much of the previous work in the field has focused on n-type metal oxides and organic hole-transport materials. For solid state p-type DSSCs (and tandem devices) an electron transport mediator is required. We will investigate the possibility of using this approach in p-type DSSCs because of the beneficial influence of the C60 accepting, storing, and transporting electrons. In this work, the fulleropyrrolidines were characterized by UV-Vis, IR spectroscopy, 1H NMR, 13C NMR and HR-Mass Spectrometry. Cyclic voltametric studies reveal that all the derivatives exhibit four reversible redox waves for each compound. The derivatives will test as electron transport mediators in DSSC, and we are predicting to show high efficiency.