Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV22)
DOI: https://doi.org/10.29363/nanoge.hopv.2022.143
Publication date: 20th April 2022
Organic-Inorganic Perovskites solar cells (PSCs) have shown power conversion efficiencies (PCE) up to 25.7% in less than a decade. [1] However, the key challenge towards the commercialization is its long-term operational instability, often originating due to mismatched interfaces. Interface engineering has been extensively used to passivate the chemical defects in the perovskite films leading to both, performance and stability enhancement. In this work, we employ the idea of surface polishing to eliminate defects/the presence of amorphous phases on the surface of perovskite film. [2,3] Application of a high-intensity laser pulse partially etches the defective perovskite film and helps in grain growth by recrystallization. [4]
We use a pulsed UV laser beam on the crystallized perovskite film and optimally tune laser power to polish the surface without compromising the short-circuit current density (Jsc). As an effect of polishing, surface roughness decreases, and photoluminescence increases resulting from the suppression in the non-radiative recombination. The device data also shows significant enhancement in FF by an absolute >4% and Voc increment of >15 meV confirming the reduction in interface losses. As a result, overall PCE increases. The results show a great potential of laser polishing in reliable, well-controllable, and scalable surface treatments in PSCs.