Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV22)
DOI: https://doi.org/10.29363/nanoge.hopv.2022.109
Publication date: 20th April 2022
This talk will present recent progress in the development of a new way to fabricate high performance transparent silver grid electrodes matched to the needs of organic photovoltaics: The electrodes have an average far-field transparency of 88%, a sheet resistivity of 6 ohm/sq, low (tuneable) surface roughness and can be fabricated on flexible plastic as well as glass. Electrodes of area 25 cm2 exhibit a less than 5% change in sheet resistance after 100,000 bending cycles through a radius of curvature of 6 mm. The silver grid is fabricated using a new iteration of a novel approach to patterning metal films developed in the Hatton laboratory, based on selective metal deposition by condensation coefficient modulation.[1,2] Using this approach embedded silver grid electrodes with micron-sized linewidth are realised, which is more than 10 times narrower than can be achieved using the conventional printing techniques of screen, inject and flexographic printing. This novel approach to grid electrode fabrication removes the need for harmful metal etchants and slow, chemical intensive electrochemical deposition steps. A performance of 10% power conversion efficiency in model OPV devices using these electrodes is comparable to that achieved using a conventional ITO coated glass electrode.