Sensitive time-resolved luminescence spectroscopy of CIGS solar cells combined with spatial resolution
Eugeny Ermilov a, Volker Buschmann a, Christian Oelsner a, Frank Birke a, Matthias Patting a, Rainer Erdmann a
a PicoQuant GmbH, Rudower Chaussee 29, Berlin, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Poster, Eugeny Ermilov, 123
Publication date: 11th May 2021
ePoster: 

Over the years, luminescence spectroscopy has established itself as one of the fundamental methods for analyzing the photophysical properties of a variety of samples, ranging from simple organic molecules to semiconductor materials and photovoltaic (PV) devices. Combining spectral and lifetime information of a sample’s luminescence signals provide a deeper insight into its photophysical processes. This can be further enhanced by including spatial information. Acquiring steady-state and time-resolved spectroscopic data at multiple, well defined points of interest (POI) of the sample can help in inferring structural-to-photophysical relationships in PV materials. Gathering such information is an important step toward the optimization of structure as well as preparation process of such materials in order to increase the performance of PV devices.

Here we will demonstrate the performance of a spectrometer-microscope assembly based on the FluoTime300 spectrometer and FluoMic add-on for investigating a Copper Indium Gallium Selenide (CIGS) based solar cell in terms of steady-sate and time-resolved luminescence spectroscopy at different micrometer sized POIs. We will show that acquiring data at well defined excitation / detection areas can provide deeper insights into relationships between structure and photophysical behavior of CIGS solar cells. This additional information are not readily available when investigating such a sample with a conventional spectrometer as the luminescence signal is averaged over a much lager area (typically 1 mm2 or more).

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