Dye-sensitized and Perovskite Solar Cells with Record Level Efficiencies
Anders Hagfeldt a
a Department of Chemistry – Ångström Laboratory, Uppsala University, Box 523, Uppsala, Sweden
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Invited Speaker, Anders Hagfeldt, presentation 119
Publication date: 11th May 2021

Some years back we introduced alkoxy functionalized donor groups as a building block in organic dyes as light harvesters for DSSC. This donor group provides a desirable 3-dimensional structure that aids in surface protection of electrons injected into the semiconductor from oxidants in the electrolyte, allowing for record-setting cobalt- and copper-based redox shuttles to be utilized more frequently. With these systems we recently set a certified world record efficiency for DSSC of 13%. DSSCs are ideally suited for ambient light and indoor applications where efficiencies up to 35% have been reached calculated with respect to the fluorescent light source.

For perovskite solar cells we have developed methods to accomplish a stable FAPbI3 phase. We found, for example, that a film of the photoinactive yellow δ- phase was converted to a highly crystalline black α-phase by vapor exposure to methylammonium (or formamidinium) thiocyanate at 100°C, and it retained this structure after 500 hours at 85°C. We have also introduced an anion engineering concept that uses the pseudo-halide anion formate (HCOO−) to suppress anion-vacancy defects that are present at grain boundaries and at the surface of the FAPbI3 films. The resulting solar cell devices attain a power conversion efficiency of 25.6 per cent (certified 25.2 per cent). In our most recent work we have obtained record level efficiencies of of 23.3%, 21.7% and 20.6% with active areas of 1, 20 and 64 cm2, respectively.

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