Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Publication date: 11th May 2021
Halide perovskites have been widely explored in photovoltaics research due to their outstanding properties as light absorbing materials. The most efficient devices use Pb-based halide perovskite. PbI2 and PbBr2, together possibly with oxide/hydroxides, are the most likely decomposition products if cells are broken and the perovskite is exposed to the ambient. These decomposition products show some solubility in water, so rain can lead to Pb reaching the groundwater. Such a scenario carries environmental and public health risk. We show here how to mitigate and even eliminate this scenario by efficient sequestering of lead. We show a scheme of ligands for sequestration as part of an encapsulation, using commercially viable materials and methods, reaching till now 85% lead retention within insoluble products (that can be removed from a disaster zone, i.e., reduce the problem to that of commercial CdTe-based cells), using commercially viable materials and methods.