Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Publication date: 11th May 2021
In the past decade, the emergence of non-fullerene small molecules for organic photovoltaics (OPV) have led to an enhancement of the power conversion efficiency (PCE) up to over 18% for bulk heterojunction (BHJ) devices [1]. Not only the favorable electronic and optical properties of these chemically tunable materials are fundamental to achieve such high performance, but also obtaining optimal nanoscale phase separation and appropriate crystallization is crucial, while unique for each combination of donor and acceptor. In this work, we present the influence of different post-annealing processes on the morphology and performance of additive-free BHJ solar cells based on donor Poly[[ 2,2'-[[4,8-Bis[4-fluoro-5-(2-hexyldecyl)-2-thienyl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]-2,5-thiophenediyl(5,6-dihydro-5-octyl-4,6-dioxo-4Hthieno[3,4-c]pyrrole-1,3-diyl)-2,5-thiophenediyl] (TPD-3F) and small molecule acceptor 9-Bis(2-methylene-((3-(1,1-dicyanomethylene)-6,7-difluoro)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2’,3’-d’]-s-indaceno[1,2-b:5,6-b’]dithiophene (IT-4F) [2]. An increase of 25% in PCE compared to the device with as-cast blend film was observed when using an optimized solvent vapor annealing post-treatment process [3], leading to over 14% of average PCE and a maximum 76% of geometric fill factor, which is among the highest reported values for additive-free BHJ solar cells. Thermal annealing and vacuum drying processes were performed in parallel for further comparison. Electrical, morphological and photophysical characterizations were performed to gain insight into these results.