Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Publication date: 11th May 2021
Light is ubiquitous in the urban environment – from the sun that shines down upon us to the artificial sources that light-up our devices and homes. While some of this light is used very effectively, for example by plants in the process of photosynthesis, much is wasted, either due to inefficient harvesting or poor recycling of the broad spectrum of wavelengths available. Spectral conversion materials provide a potential solution to this problem, using a photoluminescence process to convert available photons into energies that can be used more effectively.[1] If such materials are integrated within a suitable host, they may provide additional features such as concentration of diffuse light, improved mechanical properties and the potential to retrofit to existing photovoltaic device installations.
In this talk, recent highlights from our research into the bottom-up design of spectral converters based on organic-inorganic hybrids will be presented. It will be shown that materials chemistry design strategies can be used to control the packing, orientation and placement of lumophores, which provides a means of modulating the optical properties – from enhanced photoluminescence quantum yields[2], to tunable emission colour via Förster resonance energy transfer.[3,4] These characteristics can be exploited to improve light-harvesting and trapping within the integrated material, which can be used to develop highly efficient spectral converters for luminescent solar concentrators[5] or as optical amplifiers for visible light communications.[6] New results on the use of these hosts for triplet-triplet annihilation upconversion will also be presented.
The work presented is only possible due to the efforts of my fantastic research group (past and present) and collaborators, including: Adarsh Kaniyoor, Niamh Willis-Fox, Morton Lyu, Ilaria Meazzini, Barry McKenna, Abigail R. Collins, Bolong Zhang, Ana R. Bastos, Tiago Silvério, Paulo S. André, Rute A. S. Ferreira, Sebastien Clement and Ulrich Scherf. Financial support from the European Research Council (grant no. 818762: SPECTRACON) and Science Foundation Ireland is also acknowledged.