Photochromic dyes: new players for the fabrication of semi-transparent solar cells showing variable optical transmission
Johan Liotier a, Valid-Mwatati Mwalukuku a, Samuel Fauvel a, Pascale Maldivi a, Antonio Jesus Riquelme b, Juan Antonio Anta b, Renaud Demadrille a
a Univ. Grenoble Alpes, CEA, CNRS, IRIG, SyMMES, F-38000 Grenoble
b University Pablo de Olavide, Ctra. de Utrera, 1, Seville, Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Invited Speaker, Renaud Demadrille, presentation 009
Publication date: 11th May 2021

Among emerging photovoltaic technologies, Dye-Sensitized Solar Cells (DSSC) represent a promising and appealing class of solar cells. In the last years, they have attained quite high efficiencies and stability, and they have demonstrated their potential to convert energy under non-ideal operating environments, including indoor. [1-2] They can be fabricated using low-cost manufacturing process and materials. More interestingly, these solar cells can be colourful and semi-transparent, which makes them appealing for use in Building-Integrated Photovoltaics (BIPV). [3-4]

However, when developing semi-transparent DSSCs, a trade-off has to be found between transparency and efficiency. Current state-of-the-art only allow for the fabrication of solar cells showing an optical transmission that is fixed during the fabrication process. For the development of smart photovoltaic windows and their massive integration in buildings, variable and self-adaptable optical properties would be very valuable.

To tackle this challenge, we recently proposed a new approach based on the development of photochromic sensitizers. In this communication, we will present our strategy to prepare photochromic dyes for use in DSSCs. We will discuss the structure-properties relationships of these photochromic molecules and we will show how they can be used to develop a new generation of functional solar cells capable to change their colour, self-adjust their transparency and their photovoltaic energy conversion depending on the daylight intensity. [5]

We will also discuss the factors influencing the photochromic behaviour and the photovoltaic properties of this new class of dyes in device configuration.

R. D. acknowledges the European Research Council (ERC) for funding. This work was funded under the European Union's Horizon 2020 research and innovation programme (grant agreement number 832606; project PISCO).

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