High-Performance Cu Mesh Transparent Conductive Electrodes for Flexible Organic Photovoltaics
Philip Bellchambers a, Silvia Varagnolo a, Ross Hatton a
a Department of Chemistry, University of Warwick, CV4 7AL, Coventry, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV19)
Roma, Italy, 2020 May 12th - 14th
Organizers: Prashant Kamat, Filippo De Angelis and Aldo Di Carlo
Oral, Philip Bellchambers, presentation 121
DOI: https://doi.org/10.29363/nanoge.hopv.2020.121
Publication date: 6th February 2020

There is a clear need for a new transparent electrode compatible with flexible organic photovoltaics (OPVs) and made from low-cost raw materials. This talk will present a high-performance copper (Cu) electrode based on a Cu grid fabricated by soft lithography and demonstrate its utility in PV devices with ~10% efficiency. Even before the addition of an anti-reflecting charge transport layer the electrode has an average far field transparency of ≥ 85% which is achieved for a sheet resistance < 10 Ω sq-1. The novelty of the fabrication process is twofold: (i) an extremely rapid and clean metal etch process using a low toxicity etchant (ii) an ultrathin mask which can remain in place after etching without consequence, which together speed up and simplify electrode fabrication and integration into OPV devices. At ~1% the material cost of comparable Ag-mesh electrodes, we show these electrodes can compete with indium tin oxide (ITO) as the transparent electrode in high-performance OPVs with further advantages through their inherent flexibility.

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