Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV19)
DOI: https://doi.org/10.29363/nanoge.hopv.2020.058
Publication date: 6th February 2020
Halide perovskites are exciting materials for a range of optoelectronic devices. One of their most tantalizing features is the potential for tunable emission with high luminescence yields. Such properties are promising for reaching the radiative efficiency limits in single and multi-junction solar cells as well as color-tunable light-emitting diodes. However, there are a number of challenges in mitigating all defects in order to attain high luminescence yields and color stability across a range of bandgaps.
Here I will present a selection of our group’s ongoing work to understand the nature of defects leading to non-radiative power losses in a range of halide perovskite films, crystals and device systems, and how we can use this information to push materials and devices towards their efficiency limits. We use a selection of nano- and micro-scale imaging techniques including photoluminescence, photo-emission and nano-X-Ray-Diffraction microscopy to visualise the impact of defects and strain on local charge carrier recombination. We also employ passivation techniques designed to remove these spatially heterogeneous losses, which we demonstrate on a variety of systems. Finally, we show that these approaches ultimately lead to tangible improvements in solar cell and LED performance and bandgap stability.