Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Publication date: 21st February 2018
Antimony Sulfide (Sb2S3) solar cells improved notably over the past years and state-of-the-art efficiencies exceed 7% in a sensitized device architecture. Progress in fabrication was achieved by introducing a spin-coating process of Sb2S3 instead of the time-consuming Chemical Bath Deposition that also leads to oxygen impurities. Apart from these promising results, thorough material and device characterization is required to judge the prospects of Sb2S3 as an absorber material for solar cells.
Here, we present spin-coated Sb2S3 solar cells in a planar device geometry. Different processing routes lead to device efficiencies between 3% and 4% which is on the same level as the highest reported efficiencies for similarly processed samples. Apart from the film morphology regarding crystal size and the presence of pinholes, the choice of polymeric hole transport layer is crucial. Results from current-voltage measurements are supported by advanced device characterization such as impedance spectroscopy. We discuss efficiency limitations based on insights from device analysis and relate them to material properties such as disorder and mobility-lifetime product obtained from Photothermal Deflection Spectroscopy (PDS) and Constant Photocurrent Measurements (CPM), respectively.