Bandgap tuning of mixed-cation lead halide perovskites for tandem applications
Kunal Datta a, Martijn M. Wienk a, René A. J. Janssen a
a Molecular Materials and Nanosystems, Eindhoven University of Technology, Netherlands, Netherlands
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Kunal Datta, 293
Publication date: 21st February 2018

Tandem solar cells enable achieving high power-conversion efficiency by simultaneously reducing thermalization and transmission losses through the selective absorption of solar radiation in wide- and narrow-bandgap semiconductors. To facilitate this high performance, the bandgap of sub-cells must be matched, especially in the case of monolithic series-connected configurations. Aiming at tandem devices incorporating one or more perovskite layers, we have investigated bandgap tuning for mixed formamidinium (FA) and methylammonium (MA) lead halide perovskites using the halide tuning strategy. By employing a two-step casting process, the bandgap was tuned between 1.57 eV and 1.74 eV, leading to device efficiencies exceeding 17%, for the narrow-bandgap compositions, and 15%, for the wide-bandgap perovskites, when developed in the p-i-n device structure. We study these perovskites through X-Ray Photoelectron Spectroscopy and correlate their composition with the optical bandgap, crystal structure, morphology, photovoltaic performance and stability as a stepping stone to optimized mixed-cation perovskites demonstrating high performance and stability characteristics.

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