Influence of Hole Transport Layers : Nickel Oxide and PEDOT:PSS in Lead Iodide perovskite Solar Cells
Namrata Pant a, James Ryan b, Masatoshi Yanagida a b, Yasuhiro Shirai b, Kenjiro Miyano b
a Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi
b Global Research Center for Environment and Energy based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS)
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Namrata Pant, 261
Publication date: 21st February 2018

Methyl ammonium lead iodide perovskite solar cells have been a burning topic of research in the photovoltaic community for the past 5-6 years now. The exponential rate at which the efficiency of these Solar cells has increased from a mere 3.9 % to over 22% in less than 10 years of research is commendable. Undoubtedly, the excellent opto-electronic properties associated with perovskite (absorber layer), such as a very high light absorption coefficient, balanced charge transport properties, along with good charge carrier mobility, contribute significantly towards the device performance, studying perovskite solar cell devices with different charge transport layers can help in understanding the different properties and mechanisms observed in these devices.

Charge transport layers play an important role in enhancing the performance of the perovskite solar cells. In majority of the high efficiency devices, these layers are organic. On one hand where the organic layers have shown to be contributing towards better device parameters, the challenge associated with them is that owing to their organic nature, they also contribute to environmental instability. In order to have devices with longer lifetime, there is a need to replace the organic charge transport layers with the inorganic ones.

In this work, we have fabricated devices with two different type of hole transport layers (HTLs): PEDOT: PSS (organic) and Nickel Oxide (Inorganic). The devices have an inverted structure. Two step diffusion method was adopted for the fabrication of the devices. It is well known that the substrate has a direct influence on determining the crystallinity and morphology of the perovskite layer, which further influences the device properties.Structural and optical characterizations were carried out to study the effect of these HTLs on the device performance. In addition to this, the charge carrier dynamics were also discussed by the results of the transient voltage & current measurements.

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