Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Publication date: 21st February 2018
In recent years, significant progress in organic semiconducting materials development and device engineering has boosted the power conversion efficiency of organic photovoltaic (OPV) devices up to the commercialization threshold. However, the bulk-heterojunction active layer film forming process for high performance organic solar cells mostly achieved by halogenated solvents such as chloroform, chlorobenzene, or o-dichlorobenzene, which is harmful to health and environment. Hence, it is mandatory to develop environmental friendly solvent processing technology for greener, cheaper and large area OPV device fabrication. Recently, we have reported new molecular materials (BQR) with OPV device efficiency of 9.4% using halogenated solvent (chloroform) along with fullerene acceptor. Here, we have studied the performance of BQR with various halogen-free solvents (toluene, xylene, mesitylene etc.,) and the OPV device processed with toluene exhibits the best device performance of 10.8% with a high fill factor of 77%. The halogen-free solvent improves active layer film formation and nanoscale morphology comparing to the halogenated solvent. We have also explored the device performance and characterisation with various anode interlayers including metal oxides, towards the fabrication efficient and air-stable devices.