Defect Physics and (In)Stability in Metal-halide Perovskite Semiconductors
Annamaria Petrozza a
a Center for Nano Science and Tecnology, Istituto Italiano di Tecnologia, Via Pascoli 70/3, Milano, Italy
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Invited Speaker, Annamaria Petrozza, presentation 193
DOI: https://doi.org/10.29363/nanoge.hopv.2018.193
Publication date: 21st February 2018

Semiconducting metal-halide perovskites present various types of chemical interactions which give them a characteristic fluctuating structure sensitive to the operating conditions of the device, to which they adjust. This makes the control of structure-properties relationship, especially at interfaces where the device realizes its function, the crucial step in order to control devices operation. In particular, given their simple processability at relatively low temperature, one can expect an intrinsic level of structural/chemical disorder of the semiconductor which results in the formation of defects.

Here, first I will present our results on the role of structural and point defects in determining the nature and dynamic of photo-carriers in metal-halide perovskites. Then, I will discuss our understanding of key parameters which must be taken into consideration in order to evaluate the suscettibility of the perovkite crystals (2D and 3D) to the formation of defects, allowing one to proceed through a predictive synthetic procedure. Finally, I will show the correlation between the presence/formation of defects and the observed semiconductor instabilities/degradation.

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