Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
DOI: https://doi.org/10.29363/nanoge.hopv.2018.070
Publication date: 21st February 2018
In the first part of the talk I will present recent progress in the field of short-wave infrared colloidal quantum dot solar cells, as promising solution processed platform to harness solar energy beyond Silicon´s, CIGS´ or even perovksites´ reach. I will describe the challenges associated in high performance SWIR CQD solar cells and the tools available to engineer their energy levels and trap passivation towards high performance [1]. Then I will present preliminary results on all-CQD tandem solar cells that employ a one-atom thick graphene as intermediate recombination layer eliminating the need for vacuum-based deposition of multiple metal oxide sputtered layers or use of metal nanoparticles.
In the second part of my talk I will discuss recent progress on synergistic surface and architecture engineering of CQD solar cells to minimize trap state density and reach high open circuit voltages [2, 3]. I will conclude by showing some correlations on the performance of CQD solar cells with CQD light emitting diodes that point to the fact that a CQD thin film should yield both high efficiency solar cells and light emitting diodes.
[1] Y. Bi, S. Pradhan, S. Gupta, M. Z. Akgul, A. Stavrinadis, G. Konstantatos Adv. Mater. [Online DOI: 10.1002/adma.201704928] (2018)
[2] Breaking the open-circuit voltage deficit floor in PbS quantum dot solar cells through synergistic ligand and architecture engineering S. Pradhan, A. Stavrinadis, S. Gupta, S. Christodoulou, G. Konstantatos ACS Energy Lett. 2, 1444-1449 (2017)
[3] Trap-state suppression and improved charge transport in PbS quantum dot solar cells with synergistic mixed-ligand treatments S. Pradhan, A. Stavrinadis, S. Gupta, Y. Bi, F. Di Stasio, G. Konstantatos Small 13, 1700598 (2017)