Influence of the Presence of a Mesoporous Electron Extraction Layer on the Stability of Hybrid Perovskite Solar Cells.
Alejandra Maria Castro Chong a, Tom Aernouts b, Gerko Oskam a, Weiming Qiu b, Joao Bastos b
a Department of Applied Physics, CINVESTAV-IPN, Ant. Carr. a Progreso km 6, Cordemex, Mérida, Yucatán, 97310, Mexico
b IMEC, Thin-Film Photovoltaics, PV department, Kapeldreef, 75, Leuven, Belgium
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Alejandra Maria Castro Chong, 036
Publication date: 21st February 2018

Hybrid organometal halide perovskite solar cells (PSCs) are a potentially low cost and efficient photovoltaic technology, however, the instability of the perovskite represents a major drawback. PSCs emerged from the dye-sensitized solar cell (DSSC) in 2009, but also share several characteristics with organic photovoltaics (OPV). Since then, the efforts of the community to optimize the device configuration gave rise to two different groups of architecture: mesoscopic and planar. Advantages of using either of these architectures is still under debate since both have demonstrated certified efficiencies in excess of 20%. Clearly the mesoporous film is not essential for achieving high efficiency PSCs, however, there is evidence that the presence of a mesoporous electron transport layer (ETL) may improve the lifetime of the cells. This enhanced stability is suggested to be related to the speed of electron extraction from the perovskite layer, thus preventing a light induced degradation mechanism.

In this work, we test the stability of non-encapsulated planar and mesoscopic devices containing TiO2 as ETL in air under conditions of relatively high humidity (60% RH ± 5%). The cells were exposed to the ambient and kept either under illumination or in dark. We found that the lifetime of the mesoscopic devices is higher with a T50 value more than double that found for planar devices. We also present impedance spectroscopy results on both configurations in order to relate the electrical properties with the enhanced stability. These are important findings since it affects not only considerations about the more advantageous solar cell architecture, but also suggests the importance of choosing a proper ETL material and nanostructure.

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