Functionalized Porphyrins as New Hole-Transporting Materials for High Performance Perovskite-Based Solar Cells
Chen-Yu Yeh a, Hsien-Hsin Chou a, Yu-Hsien Chiang b, Peter Chen b
a National Chung Hsing University, Department of Chemistry, Taiwan, Guoguang Road, 250, Taiwan, Republic of China
b Department of Photonics, National Cheng Kung University, No.1, University Rd. , Tainan, 701, Taiwan, Republic of China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Hsien-Hsin Chou, 310
Publication date: 28th March 2016

Perovskite-based solar cells (PSCs) are the most fascinating solar-to-electricity converting technologies in the new century. The urge of searching for alternative hole-transporting materials (HTMs) for high-performance perovskite-based solar cells is growing. Rencently we have developed new category of porphyrin-based hole-transporting materials which are structurally simple, easy to prepare and well performed. For PSC device based on porphyrin HTM Y2, high performance with PCE of 13.82% with open-circuit voltage (VOC) and short-circuit current (JSC) of 1.01 V and 20.88 mA cm-2, respectively, is observed comparable to that based on Spiro-OMeTAD where PCE = 14.67% (VOC = 1.04 V and JSC = 20.87 mA cm-2). However, the long chain tethered Y2A2 shows lower PCE of 10.55% (VOC = 1.01 V; JSC = 17.80 mA cm-2). It is found that Y2 and Spiro-OMeTAD are of similar HOMO level and of the same order of hole mobility at 10-4 cm2 V-1 s-1. Our results offer new class of high performance hole-transporting materials for perovskite-based solar cells. To our knowledge, it is the highest-performance solar cell device (including dye-sensitized solar cells and organic photovoltaics) ever reported that is incorporated with porphyrin materials.



© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info