Vertically Aligned CNTs as Electrodes in Perovskite Based Optoelectronic Devices
Pavao Andricevic a, Jérôme Philippe Gabathuler a, László Forró a, Balint Nafradi a, Dóra Fejes a, Endre Horvath a, Klara Hernadi b
a Laboratory of Physics of Complex Matter (LPMC), Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland
b Department of Applied and Environmental Chemistry, University of Szeged, Rerrich Béla tér 1, HU-6720 Szeged
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Pavao Andricevic, 295
Publication date: 28th March 2016

In various optoelectronic applications, like light-emitting diodes, photodetectors and photovoltaic cells, carbon nanotubes (CNTs) have been successfully used due to their outstanding electronic and mechanical properties. Special set of reaction conditions allow carbon nanotubes to self-assemble into vertically oriented cellular arrays during growth on a substrate. This special architecture of CNTs, the carbon nanotube forests, have come to the focus of research in nanoscale science, since the alignment offers many advantages from the viewpoint of the desired application. This study aims to show that vertically aligned CNTs can be used as efficient hole or electron selective electrode contact materials for future perovskite based optoelectronic devices.  As an example, we examined the electronic properties of the interfaces composed of millimeter long vertically aligned carbon nanotube forest and methylammonium lead halide and mixed halides CH3NH3PbX3 (X = Cl, Br, I) perovskites. The photovoltaic perovskites have been synthesized in various shapes and forms; millimeter large single crystals and elongated nanowires. Photosensitive interfaces were prepared by bringing the perovskites and carbon nanotubes in contact by wet chemical deposition or by a “solvent-free dry pressing” method. The I-V characteristics of the devices have been determined in the dark and under visible light, UV and X-ray illumination. We found that vertically aligned carbon nanotubes serve as a versatile platform for future selective electrode development. 

 

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