Long Alkyl Chain Modified Grahene Oxide as Encapsulation Material for Perovskite Solar Cell
Chun-Yu Chang a, Pei-Huan Lee a, Wei-Fang Su a
a National Taiwan University of Science and Technology, Taipei, Taiwan, Republic of China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Pei-Huan Lee, 277
Publication date: 28th March 2016

Organic-inorganic metal halide perovskite solar cells have attracted lots of attention due to its excellent optical and electronic properties.The highest certified power conversion efficeincy (PCE) is over 22%. However, the organic-inorganic metal halide perovskite is very sensitive to the moisture, which would affect the long-term stability of devices. How to avoid the moisture degradation of perovskite material is a challenge problem. In this work, we develop a facile encapsulation technique to improve the long-term stability of perovskite solar cells. We introduce octadecylamine modfied graphene oxide (ODA-GO) as encapsulation materials and combine with polydimethylsiloxane (PDMS) to form a conformalseal on the device. Because both materials are hydrophobic, they areeffective to prevent the moisture  reacting with perovskite materials. We systematically study the relationship between the degree of ODA functionalization andthe moisture permeation of the ODA-GO.Finally, by optimizing the blending ratio of the ODA-GO/PDMS composite film, the stability of the solar cell can be greatly improved.



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