Perovskite CH3NH3PbI3 Materials –Ultrasonic Spray Method for Preparation
Carita Kvarnström a, Mika Lastusaari a, Esa-Pekka Mattila a, Eerik Salonen a, Pia Damlin a, Mikko Salomäki a, Minnea Tuomisto a b, Polona Umek c, Melita Sluban c
a Turku University Centre for Materials and Surfaces (MATSURF), Laboratory of Materials Chemistry and Chemical Analysis, University of Turku, Vatselagatan, 2, Åbo, Finland
b University of Turku Graduate School (UTUGS), Turku, FI-20014, Finland
c Jožef Stefan Institute, Ljubljana, SI-1000
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Minnea Tuomisto, 218
Publication date: 28th March 2016

Semiconducting perovskite materials have shown highly competitive optical and electronic properties in photovoltaic applications such as solar cells. For solar cell applications studies of both basic materials and films are extremely necessary. In this work, organic-inorganic hybrid perovskite CH3NH3PbI3 -films were fabricated by an ultrasonic-assisted spray method. Synthetized CH3NH3I -material and PbI2 were used as precursors. The films were fabricated by spraying the precursors on surfaces of selected rotating substrates using a heated air flow. The distance to the surface, the rate of the flow and the temperature of the air were optimized. The perovskite films were studied in multilayer configuration where the other layers consisted of titanium dioxide nanoribbons, and a hole blocking layer. Eventually a cell was constructed and tested. The perovskite material was also prepared as powder with a standard solution method for comparison. The materials were characterized using X-ray diffraction, scanning electron microscope (SEM), ellipsometry and X-ray fluorescence spectroscopy (XRF).



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