Transient Photovoltage (TPV) Study on Organic Solar Cells
Jiaying Wu a, James Durrant a
a Imperial College London, United Kingdom, South Kensington, Londres, Reino Unido, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Jiaying Wu, 193
Publication date: 28th March 2016

The creation of bulk heterojunction architecture enabled a substantial increase on device performance of organic solar cells, and this device structure has become the most widely used at present(Yu, Gao et al. 1995). Although, this intimate mixing structure large increase the exiton dissociation, the recombination separated polarons also substantially increased due to large interface area. This recombination also known as the non-geminate recombination becomes the main loss process in bulk heterojunction organic photovoltaics device (Koster, Mihailetchi et al. 2005, Koster, Mihailetchi et al. 2006). In order to achieve higher device performance, the study of physical mechanism of non-geminate recombination is of crucial significance. To study the non-geminate recombination dynamics, our research employs a combination of charge extraction (CE) and transient photovoltage/photocurrent (TPV/TPC) to experimental quantify the carrier density and lifetime respectively. My current work studied:        

1. TPV/TPC/CE study on thickness and light intensity dependence of polymer/fullerene solar cells.        

2. Voc loss mechanism of degraded organic photovoltaics device.        

3. Effects of electrode charge on organic solar cells.    

Koster, L. J. A., et al. (2006). "Bimolecular recombination in polymer/fullerene bulk heterojunction solar cells." Applied Physics Letters 88(5): 052104.               

Koster, L. J. A., et al. (2005). "Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells." Applied Physics Letters 86(12): 123509.               

Yu, G., et al. (1995). "Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions." Science 270(5243): 1789-1791.                



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