Porous Titania for Metal Ion Removal and Pb2+@TiO2 as Photoanode in Efficient Dye Sensitized Solar Cell
Jayraj Vaghasiya a, Saurabh Soni a, Bharat Solanki a
a Sardar Patel University, Department of Chemistry, S P University, Near University Circle, Vallabh Vidyanagar, 388, India
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Saurabh Soni, 166
Publication date: 28th March 2016

Porous titania is a promising materials in environmental and energy sector, the improvement of the sensitivity is of social importance, which can be achieved by making highly structured anatase titania. Titania with anatase form is extensively used as a photocatalyst for remediation of contaminated water, air and as photoanode in solar cell. At the nanometer scale, its efficiency is greatly enhanced by the increased in surface area of the particles and modification of their optical properties due to size quantization. So far, the nanoporous titania has been used to remove toxic metal ions from water but disposable of these hazardous metals after removal is a problem. At the same time, metal doped nanoporous titania also in use as photoanode to control the electron recombination in dye sensitized solar cell. Here in, we prepared ionic liquid templated hierarchically porous titania which is used to remove toxic metal ion, lead (CPb2+ = 0.01M) from water. Porous titania efficiently (~ 97%) remove lead ion from water by simple filtration. The nanoporous titania before and after metal extraction was characterized by using XRD, EDAX, CV, Mott-Schottky etc. The lead ion embedded porous titania was used as a photoanode in dye sensitized solar cell (DSSC). The DSSC device shows enhancement in photocurrent, voltage and thus photo-conversion efficiency. The results will be compared with the device fabricated with undoped and commercially available titania nanoparticles (P25). References: [1] Chen, X.; Mao, S. Chem. Rev. 2007, 2891. [2] Moula et. al. J. Nanomater. Mol. Nanotechnol, 2013, 51.



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