Chemical Vapor Deposition for Thiocyanate-Based Perovskite Solar Cells
Yu-Hsien Chiang a, Peter Chen a b
a Department of Photonics, National Cheng Kung University, No.1, University Rd. , Tainan, 701, Taiwan, Republic of China
b Research Center for Energy Technology and Strategy (RCETS), National Cheng Kung University, No.1, University Rd., East Dist., Tainan, 701
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Yu-Hsien Chiang, 056
Publication date: 28th March 2016

Hybrid inorganic-organic perovskite solar cells have been the spotlight in solar cells in the past few years. The long-term device stability and high power conversion efficiency are of crucial importantance for commercialization. In this report, we fabricate thiocyanate-based perovskite solar cells with chemical vapor deposition (CVD) method. Scanning electron microscopic image shows that SCN-based perovskite films via CVD have uniform morphology and large grain size at least 200 nm. These results reveal that the chemical vapor deposition can grow high-quality pseudohalide pervoskite films. For measuring the crystal structure of CH3NH3Pb(SCN)2I, the X-ray diffraction is employed to observe the characteristic peaks for both SCN-based and pure CH3NH3PbI3 pervoskite. The distinct peak of (110) at 14.16o for pure CH3NH3PbI3 is slightly shifted to 14.49o for CH3NH3Pb(SCN)2I. We suggest that the thiocyanate incorporates into perovskite crystal and distorts the lattice. The UV-vis spectra shows that the absorption onset of CH3NH3Pb(SCN)2I is identical with pure CH3NH3PbI3 at 780 nm. Moreover, we observe that the signal of photoluminescence(PL) for CH3NH3Pb(SCN)2I is at 770 nm. The higher radiative recombination energy level may produce higher open-circuit voltage(Voc)which is beneficial for high performance solar cells. Using Chemical vapor deposition method, we prepare SCN-based perovskite solar cells which produce a power conversion efficiency of 12.72%. These results demonstrate the pseudohalide perovskite solar cells are the promising material for improving stability and replacing pure CH3NH3PbI3 system. 



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