Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Publication date: 28th March 2016
In recent years, organic–inorganic halide perovskites have become increasingly popular and promising as photovoltaic materials for third-generation solar cells. The electron-selective layer (ESL), one of the most important components in highly efficient PSCs, is responsible for the extraction of the photogenerated electrons and simultaneously serves as a blocking layer to prohibit the direct contact of the conductive substrate with the hole-transport material (HTM) and the metal cathode. The strategies established for the low-temperature fabrication of inorganic ESLs are generally based on nanocrystallites that guarantee the desired electronic properties of ESLs. As we know, it is very facile to obtain amorphous inorganic materials at very low temperatures; however, amorphous inorganic ESLs for PSCs have been rarely reported up to now.WOx, SnO2, and ZnO are common oxide semiconductors with high electron mobility and other special electronic properties. Our group studied these three kinds of ESLs material for PSCs. We will report our recent results, especially, about the one facile solution route to successfully fabricate inorganic, amorphous WOx-based composite ESLs at the very low temperature of 70 °C and at room temperature for efficient planar PSCs. The flexible PSCs generated a high PCE of 11%. More inspiringly, the rigid PSCs using the ESL that were prepared at 25 °C, also achieved PCEs exceeding 14.0%.
Reference:
1. Kai Wang, Yantao Shi, and Tingli Ma, J.Physical Chemistry Letters. 2015, 6, 755.
2. Kai Wang, Yantao Shi, Qingshun Dong, and Tingli Ma, Adv. Mater. 2015, DOI: 10.1002/adma.201505241
3. Huawei Zhou, Yantao Shi, Kai Wang, Qingshun Dong, and Tingli Ma., J.Physical Chemistry C. 2015, 31, 285
4. Qingshun Dong, Yantao Shi, and Tingli Ma. J. Phys. Chem. C, 2015, 119 (19), 10212