Multilayer Fullerene-Free Organic Solar Cells with Low Photon Energy Losses
Vasileios Christos Nikolis a, Donato Spoltore a, Johannes Benduhn a, Felix Holzmüller a, Christian Körner a, Koen Vandewal a
a Institut für Angewandte Photophysik, TU Dresden, George-Bähr-Str. 1, Dresden, 1069, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Vasileios Christos Nikolis, presentation 053
Publication date: 28th March 2016

The generation of free charge carriers at interfaces between organic electron donors (D) and electron acceptors (A) can be very efficient, enabling organic solar cells with external quantum efficiencies (EQE) higher than 80% and internal quantum efficiencies (IQE) approaching 100%. On the other hand, recombination of free charge carriers at the D-A interface reduces the open-circuit voltage (VOC) and overall power conversion efficiency (PCE) of photovoltaic devices comprising such interfaces.

We demonstrate an optimization route in order to improve the PCE and VOC in multilayer organic solar cells. The deposition of an ultrathin interlayer between D and A creates a discontinuous layer which reduces the D-A interface area and thus free charge carrier recombination, while keeping a high free carrier generation yield. Investigating a series of interlayer materials and multilayer device architectures, we achieve PCE’s above 7.5%. Most notably, this strategy enables a VOC of 1.16 V with a peak external quantum efficiency of 78% at 1.77 eV (700 nm). Such voltage losses below 0.61 V combined with high quantum efficiencies are among the lowest for organic solar cells.

This work provides clear pathways for the minimization of photon energy losses by manipulation of the organic photovoltaic device architecture.



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