Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Publication date: 28th March 2016
Polymer solar cells (PSCs) have been widely studied in the past fifteen years around the world. Significant efforts have been made in all aspects. The low power conversion efficiency (PCE) is one of the key barriers to realise the large-scale commercialisation. In addition, the latest organolead halide perovskite-based PV devices illustrated a rapid increase in the PCE; however, they are also facing significant challenges for the large-scale deployment because of containing highly toxic Pb in the material and poor stability. This report, for the first time, presented a novel approach for developing the light-harvesting photoactive layer for hybrid organic-inorganic photovoltaic devices. A composite photoactive layer by utilising both advantages of conjugated photoactive polymers and organolead halide perovskites has been developed in this work. Photoactive conjugated polymers include a family of organic semiconductive materials that covers a full range of wavelengths for light absorption; e.g. P3HT with 2.0 eV band gap, PTB-7 with 1.81 eV band gap, and PDPP3T with 1.56 eV band gap. This approach offers more flexibility in future in developing halide perovskite-based photoactive layers which can absorb a full-range wavelength of light without sacrificing other properties such as stability of the halide perovskites. This novel approach was demonstrated to obtain high-efficient photovoltaic devices by the solution-processed method. The performance of the photovoltaic devices were characterised. Significant stability was also enhanced compared with photovoltaic devices that are only based on the same type of halide perovskite photoactive layer. Other properties were also studied in this report.