Micrometer Size Grains of Hybrid Perovskite Through Rapid Melting Procedure
Norbert Nickel a, Bernd Rech a, Carola Klimm a, Oleksandra Shargaieva a, Felix Lang a, Jörg Rappich a, Manuela Klaus b
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Oleksandra Shargaieva, 034
Publication date: 28th March 2016

Perovskite type materials exhibit high absorption coefficient, and possibility of band gap tuning, what makes them a good option for solar cell application. One of the most important advantages of perovskite absorbers is the simplicity of preparation within low costs compared to inorganic state-of-the-art semiconductors. However, successful application is often limited by crystalline properties of materials due to solution processing. Thus, devices based on such hybrid compounds usually suffer from morphology issues.

In our work we propose new approach of morphology improvement based on rapid melting procedure. This simple treatment allows obtaining up to micrometer size grains within 1 minute. The procedure was optimized in time and temperature for gradual grain size growth in a broad range. Since the procedure is a post treatment it can be used substrate and/or sample-independent.

Changes of the crystalline state of treated samples were monitored with PL spectroscopy by increase of signal intensity and redshift. Moreover, melted samples were analyzed via XRD measurement to insure presence of the perovskite structure in the post-treated films. Consequently, application of the rapid melting technique gives a possibility to enhance the crystallinity of perovskite thin-films in precisely controlled conditions, that can be applied on industrial scale.



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