Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Publication date: 28th March 2016
Dye-sensitized solar cells have been studied extensively but only incremental increases in efficiency have been achieved over the last 25 years. One way of increasing the efficiency is to develop p/n tandem DSCs that convert the full visible-NIR region with an efficiency that cannot be reached using one photoelectrode alone. However, their potential has been relatively under-researched because the efficiency of dye-sensitized p-type semiconductors is substantially lower than what is readily achieved with conventional TiO2. My team made a significant breakthrough in improving the efficiency of dye-sensitized photocathodes by maximising the spectral response in the red region of the solar spectrum with two new push-pull photosensitizers. We reported a record photocurrent density over 8 mA cm–2 and the highest photocurrent density for a tandem dye-sensitized solar cell to date. This talk will include highlights of our recent work, including the use of time-resolved infrared absorption spectroscopy to study the charge-transfer at the NiO/dye/electrolyte interface.
Wood, C. J.; Summers, G. H.; Gibson, E. A. Chem. Commun. 2015, 51, 3915–3918.