Proceedings of International Conference on Hybrid and Organic Photovoltaics 2015 (HOPV15)
Publication date: 5th February 2015
Dye-sensitized solar cells (DSCs) represent an attractive alterative to conventional solid-state semiconductor photovoltaics due to their low fabrication cost, short energy payback time and the scope to produce these devices by high-throughput roll-to-roll printing techniques. In this talk we will focus on our recent advances in the development of novel redox mediators for their use in DSCs. We will provide some insights into the energetics of dye-regeneration by these redox mediators and its impact on regeneration yields and ultimately energy conversation efficiencies. Here we will point out the advantages of ferrocene derivatives as redox mediators that allow to fine tune the driving forces for dye-regeneration. Today’s most efficient DSCs employ cobalt polypyridyl complexes as redox mediators. We will introduce a novel class of energetically tunable cobalt complexes, coordinated by a pentadentate ligand as well as a novel cobalt complex based on a hexadentate ligand that shows dramatically increased stability, compared to the archetypical [Co(bpy)3]2+/3+ (bpy = 2,2’-bipyridine) complex.