Novel Redox Mediators for Dye-Sensitized Solar Cells
Udo Bach a b
a Monash University, AU, Calyton, 3800, Australia
b CSIRO Clayton Laboratories, Bayview Avenue, Clayton VIC, 3168, Australia
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics 2015 (HOPV15)
Roma, Italy, 2015 May 11th - 13th
Organizer: Filippo De Angelis
Invited Speaker Session, Udo Bach, presentation 276
Publication date: 5th February 2015

Dye-sensitized solar cells (DSCs) represent an attractive alterative to conventional solid-state semiconductor photovoltaics due to their low fabrication cost, short energy payback time and the scope to produce these devices by high-throughput roll-to-roll printing techniques. In this talk we will focus on our recent advances in the development of novel redox mediators for their use in DSCs. We will provide some insights into the energetics of dye-regeneration by these redox mediators and its impact on regeneration yields and ultimately energy conversation efficiencies. Here we will point out the advantages of ferrocene derivatives as redox mediators that allow to fine tune the driving forces for dye-regeneration. Today’s most efficient DSCs employ cobalt polypyridyl complexes as redox mediators. We will introduce a novel class of energetically tunable cobalt complexes, coordinated by a pentadentate ligand as well as a novel cobalt complex based on a hexadentate ligand that shows dramatically increased stability, compared to the archetypical [Co(bpy)3]2+/3+ (bpy = 2,2’-bipyridine) complex. 



© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info