Proceedings of International Conference on Hybrid and Organic Photovoltaics 2015 (HOPV15)
Publication date: 5th February 2015
Electric fields that build up in a solar cell can affect their absorption spectrum due to Stark effects. In dye-sensitized solar cells (DSC) usually a spectral bleach is found upon photoinduced electron injection. Also in perovskite solar cells (PSC) photoinduced effects are found. Here we will discuss the observed Stark effects in detail and correlate them to electric fields in the solar cell and ion movements.
In the DSC, electrons in mesoporous TiO2 electrodes are charge compensated by cations in the surrounding electrolyte. Upon photoinduced electron injection, the charge compensating cations are initially located outside the dye monolayer, but transient absorption spectroscopy reveals that the Stark bleach slowly disappears (t > 0.1 s). This is attributed to penetration of cations into the dye monolayer.
In MAPbI3 perovskite solar cells a light-induced dipole moment change inside the perovskite film is found, leading to the observation of a Stark effect. Large polarizability of perovskite film in the device under working conditions is responsible for the dipole moment change. Time domain measurements show that dipole moment changes occur on the timescale of seconds, which is comparable to the timescale of hysteresis effects found in the solar cells after light excitation.