Proceedings of International Conference on Hybrid and Organic Photovoltaics 2015 (HOPV15)
Publication date: 5th February 2015
Four push-pull cyclopentadithiophene (CPDT) sensitizers exhibiting efficiencies ranging from 0.82 % to 1.67 % with different anchor groups and/or triphenylamine (TPA)-based moieties were investigated in solid-state dye-sensitized solar-cells (DSCs). We found that the best performing dye molecules show long-lived charges and high injection efficiencies. On the contrary, inefficient dye molecules exhibit short-lived charges and reduced injection efficiency (IE). In fact, the most efficient dye molecules reach injection efficiencies close to unity, whereas the less efficient dye molecules exhibit injection efficiencies of 87%. An efficient dye cation regeneration process is observed for the efficient solar cells, which show long-lived signals, while charges in the less efficient devices decay after 10 ps - 100 ps. We conclude that a combination of dipole moments, reactivity of the molecules towards Li cation additives, and the generation of long-lived dye/hole transporter (Spiro-OMeTAD) cations are essential for the better power conversion efficiency (PCE) of the devices.
Figure 1. Transient absorption kinetics of spiro cations in the solar cell-like samples.