The potential of perovskite solar cells for water splitting
Jingshan Luo a, Michael Grätzel  a
a Laboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Switzerland, Station 6, CH-1015 Lausanne, Lausanne, Switzerland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics 2015 (HOPV15)
Roma, Italy, 2015 May 11th - 13th
Organizer: Filippo De Angelis
Oral, Jingshan Luo, presentation 084
Publication date: 5th February 2015

H2 production via solar water splitting has been considered as a promising strategy to store solar energy and provide clean fuel for the future. However, the complexity and the expense of current systems hamper the large scale implementation. The emergence of perovskite solar cells provides new opportunities, mainly due to their high efficiency combined with facile solution processing, large open circuit voltage and the possibility of making them semi-transparent. Taking advantage of the large open circuit volltage of these cells, we have achieved 12.3% solar to hydrogen (STH) conversion efficiency by combining a pair of perovskite photovoltaics and Earth-abundant catalyst electrodes, which is not possible with two silicon (Si) solar cells, Fig.1. [1] Furthermore, I will talk about our most recent efforts in making a panchromatic tandem water splitting device by combining perovskite solar cell and CuIn1-xGaxSe2 (CIGS) photocathode in photovoltaic biased photoelectrochemical (PV-biased PEC) approach. Using a similar protection strategy as we previously demonstrated for Cu2O, [2] we have enabled CIGS as a stable and highly efficient photocathode, with a photocurrent density of 34 mA cm-2 and an onset potenial of 0.6 V versus reversible hydrogen electrode (RHE). A tandem of this CIGS photocathode with a high open circuit voltage and semi-transparent perovskite solar cell, achieves around 5% STH efficiency without optimizing the system.


Fig. 1. (A) A general band diagram of perovskite tandem cell for water splitting. (B) J-V curves of the perovskite tandem cell under simulated AM 1.5G 100 mW cm-2 illumination and dark condition, and the J-V curve of the NiFe/Ni foam electrodes under two electrode configuration.
[1] J. Luo, J. -H. Im, M. T. Mayer, M. Schreier, M. K. Nazeeruddin, N. -G. Park, S. D. Tilley, H. J. Fan and M. Grätzel Science, 345 (2014) 1593 [2] A. Paracchino, V. Laporte, K. Sivula, M. Grätzel, E. Thimsen, Nat. Mater. 10 (2011) 456
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