Tuning the shape of lead-methylamine iodide (CH3NH3PbI3) nanoparticles prepared by low-temperature solution-mediated crystallization
László Forró a, Richard Gaal a, Massimo Spina a, Endre Horváth a
a Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne, Switzerland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Poster, Endre Horváth, 346
Publication date: 1st March 2014

Solid-state hybrid organic-inorganic perovskite sensitized mesostructured solar cells have recently demonstrated remarkable power conversion efficiencies of 16 % at the lab scale. Despite the rapid progress in boosting up the devices' efficiencies, there is a lack of knowledge regarding some fundamental physical and chemical properties of this lately re-discovered material. The general observation is that minor alteration in the applied processing parameters may lead to dramatically different device performances. This recommends that it is critical to have fine control over the nucleation and crystal growth of the MAPbI3.

Here, we report the synthesis of lead-methylamine iodide (CH3NH3PbI3) nanoparticles by a low- temperature solution-processed crystallization method. We present structural and photo-physical characterization of thin films with altered crystallite size -and orientation. Our results provide a basis for the realization of new solution-mediated strategies with the ultimate goal of exerting control over particulate characteristics. Crystal engineering of trihalide perovskites (trough particle size and shape) will enable to explore exiting opportunities in photonics industry such as solar energy conversion, photodetectors and on-chip coherent light sources.

 

 

 

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