Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Recently, solar cells composed of perovskite compounds as absorbers attract great attention. Impressive performance was achieved not only in solid state dye sensitized solar cells,1,2but low-temperature processed organic solar cells.3 We started employing CH3NH3PbI3 in organic solar cells very recently. The progress is encouraging. Here we will present our preliminary results of solar cells based on CH3NH3PbI3.
There are several different ways to prepare or synthsize perovskite compounds. We use a two-step approach developed very recently by the Yang group.3 Photocurrent of 19 mA/cm2 was achieved with the device structure of ITO/PEDOT-PSS/ CH3NH3PbI3 /PC71BM/Al (black curve in Figure 1a). The small fill factor (FF), Voc and large dark current (Figure 1b) indicate that the efficiency of the device was mainly limited by leakage current. To prevent leakage current, a small amount of polymer (P3HT) (5%) was added into the electron-transportlayer (ETL) PC71BM. Significant improvement of FF and enlarged Voc was observed. The I-V characteristics of the solar cell suggest that the leakage current was effectively suppressed and the efficiency went up to 6% as shown in Table 1), even though the photocurrent dropped to 13 mA/cm2(red line in Figure 1a)
Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; and Snaith, H. J.; Science, 2013, 342, 341–344