Hybrid Tandem Photovoltaics Using Organometallic Perovskites as the Top Cell
Eva Unger a, Michael McGehee a, Alberto Salleo a, Andrea Bowring a, Eric Hoke a, Bailie Colin a, Greyson Christoforo b, Norman Pellet c, Michael Grätzel c, Julian Burschka c
a Department of Materials Science, Stanford University, 476 Lomita Mall, Room 201, Stanford, 94305, United States
b Department of Electrical Engineering, Stanford University, United States
c Institut de Chimie Physique, École Polytechnique Fédérale de Lausanne, Switzerland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Oral, Bailie Colin, presentation 148
Publication date: 1st March 2014

For solar energy to provide a significant fraction of the world’s electricity mix the balance of systems (BOS) cost has to be further reduced. Modules can reduce the BOS cost with improvements in performance. Hybrid tandem photovoltaics, two different semiconductor technologies used in a single tandem device, are a promising solution to improve the efficiency of the module without greatly increasing the module cost. Recent advancements in perovskite solar cells have vaulted their power conversion efficiency to over 15%. High efficiencies, low energetic losses between absorber bandgap and device voltage, low-temperature processability, cheap precursor materials, and the possibility to tune the absorber materials bandgap by simple chemical substitution, make these materials ideal candidates for use as the top cell in a double-junction tandem. We replace the opaque metal back electrode of perovskite solar cells with a solution processed silver nanowire transparent top electrode. We mechanically stack the 'semi-transparent' device in a 4-terminal tandem configuration onto CIGS cells and demonstrate the first net efficiency improvement of a commercial grade solar cell using the hybrid tandem concept. This work paves the way for integrating perovskites into a low cost and high efficiency (25-30%+) multijunction cell and highlights the potential for the mass adoption of the hybrid tandem format by the photovoltaic industry.



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