Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Four new pyrrole-based organic sensitizers with different isolation groups were conveniently synthesized and applied to dye sensitized solar cells (DSCs).The introduction of isolation group could suppress dye aggregates and electron recombination, and the various isolation groups with different size could vary the photovoltaic performance of the corresponding dyes in a large degree. Especially, when two pieces of D-π-A chromophore moieties shared one isolation group to construct the "H" type dye, the conversion efficiency increased largely. Consequently, in the corresponding solar cell of LI-57 with the "H" structure, a short-circuit photocurrent density (Jsc)was tested to be 13.85 mA cm−2,while 0.72 V for the open-circuit photovoltage (Voc), and 0.64 for thefill factor (FF),and 6.43% for the overall conversion efficiency (η), exceeding its analogue LI-55 (5.94%) with the same isolation group. These results demonstrated that both the size (bulk and shape) and the linkage mode between the D-π-Achromophores and the isolation groups, could influence their photovoltaic performance, providing a new approach to optimize the chemical structure of dyes to achieve high conversion efficiencies.
Fig.1 the structure of pyrrole-based dyes