Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Lead halide perovskites currently attracted widespread attention for photovoltaic devices due their large absorption coefficients, high carrier mobility and the possibility of controlling their optoelectronic properties. Several reports used CH3NH3PbI3 perovskite nanocrystals as sensitizers with liquid electrolyte[i], the performance of these systems rapidly declined due to dissolution of the perovskite. Recently impressive progress was achieved using spiro-OMETAD as hole conductor in solid state sensitized solar cell achieving power conversion efficiency of 15%[ii]. However using hole conductor in the solid-state sensitized solar cells can posses some problems such us difficulties in pore filling, additional resistances at the interface and stability issue which affect the possibility for long term use.
In this work a hole conductor free CH3NH3PbI3 / TiO2 heterojunction solar cell using a thick CH3NH3PbI3 film is presented. The CH3NH3PbI3 formed large crystals which function simultaneously as sensitizers and as hole transport material.
The lead iodide CH3NH3PbI3(perovskite)/TiO2 heterojunction solar cell was produced by deposition of perovskite nanoparticles from a solution of CH3NH3I and PbI2 in g-butyrolactone on a film of TiO2 (anatase) Nanoparticles.
The simple mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cell shows impressive power conversion efficiency of 8% with current density of 18.8 mA/cm2, the highest efficiency achieved so far for perovskite based solar cells without hole conductor.
[i]J.HyoekIm, C.-R.Lee, J.-W Lee, S.-W.Park, N.-G. Park, Nanoscale. 2011, 3, 4088. [ii]Julian Burschka, Norman Pellet, Soo-Jin Moon, Robin Humphry-Baker, Peng Gao, Mohammad K. Nazeeruddin1 & Michael Graetzel, Nature, 2013, 499, 316.