Selective interdigitated contacts for improved photocatalytic systems: TiO2 case study.
joaquim puigdollers a, oriol segura a, edgardo saucedo a, edoardo maggi a, lluis soler b, jordi llorca b, cristobal voz a, gerard masmitjà a
a Center for Research in Multiscale Science and Engineering and Department of Chemical Engineering, Institute of Energy Technologies, Universitat Politècnica de Catalunya (UPC), EEBE, Eduard Maristany 10–14, Barcelona, 08019 Spain
b Center for Reseacrh in Multiscale and Engineering and Department of Electronic Engineering
Proceedings of The Future of Hydrogen: Science, Applications and Energy Transition (H2Future25)
Production
Ibiza, Spain, 2025 May 5th - 7th
Organizers: Teresa Andreu, Bahareh Khezri and Jose Mata
Contributed talk, joaquim puigdollers, presentation 011
Publication date: 27th March 2025

The main objective of a solar cell is the generation of energetically and physically separated electrons and holes. These charge carriers will recombine in the external circuit providing electrical power. This separation of charge carriers is achieved by incorporating charge-selective contacts, called Hole Transport Layer (HTL) and Electron Transport Layer (ETL) respectively. The use of HTL and ETL is already widely established in almost all solar cell technologies.

The principle of operation of a photocatalytic system dedicated to the generation of hydrogen can also be described in an analogous way to a photovoltaic solar cell. Despite this analogy, the use of HTL and ETL is not well established in the manufacture of photocatalytic systems.

In this presentation we will describe the parallelism between the operating principle of a solar cell and a photocatalytic system and we will show that the incorporation of selective contacts improves the efficiency of photocatalytic systems based on Titanium oxide.

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